I wouldn't use starter fluid as it ignites violently. It could lead to a nasty whack (or worse) on the fingers or hand. Unless it is extremely cold out, our engines should start just fine using normal starting techniques.
Many of these fluids do contain a lubricant and the cans are labeled as such. As pointed out by w8ye, many do not have a lube. I wouldn't think it an issue either way though as used properly, no liquid would enter the engine ... only vapor.