RE: CG on an Accel Pitts S2C 40 Bipe
Place your fingers under the top wing on each side of the rear cabane post, and adjust the balance so the plane hangs level in the upright position. This will be slightly nose heavy, but will be a good starting CG position.
Later on as you get used to the Pitts, you can slowly move the CG back to match your personal tastes.