I would read through this thread and watch the videos Mike added to the thread

http://www.rcuniverse.com/forum/m_4459958/tm.htm

and decide which ones would be best for your current flying skill level.

Cetain manuevers can be hard for one person and easy for the next so it's hard to say which ones to start out with. If you have a decent simulator, burn loads of time on it practicing. You also need to burn a lot of fuel as well. Start up high until you are comfortable then bring it lower, get comfortable, then come lower even more.